Dichotomous reactions of thioketones with tetracarbonylferrate
نویسندگان
چکیده
منابع مشابه
Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles
Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO4 or, alternatively, under high-pressure conditions (5 kbar) at room temperature yielding thiopyran derivatives. The hetero-Diels-Alder reaction occurs in a chemo- and regioselective manner. The initially formed [4 + 2] cycloadducts rearrange via a 1,3-hydrogen shift sequence ...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1979
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v79-096